Disequilibrium Chemistry, Diabatic Thermal Structure, and Clouds in the Atmosphere of COCONUTS-2b

Abstract: Located 10.888 pc from Earth, COCONUTS-2b is a planetary-mass companion to a young (150-800 Myr) M3 star, with a wide orbital separation (6471 au) and a low companion-to-host mass ratio ($0.021\pm0.005$). We have studied the atmospheric properties of COCONUTS-2b using newly acquired 1.0-2.5 $\mu$m spectroscopy from Gemini/Flamingos-2. The spectral type of COCONUTS-2b is refined to T$9.5 \pm 0.5$ based on comparisons with T/Y dwarf spectral templates. We have conducted an extensive forward-modeling analysis, comparing the near-infrared spectrum and mid-infrared broadband photometry with sixteen state-of-the-art atmospheric model grids developed for brown dwarfs and self-luminous exoplanets near the T/Y transition. The PH${3}$-free ATMO2020++, ATMO2020++, and Exo-REM models best match the specific observations of COCONUTS-2b, regardless of variations in the input spectrophotometry. This analysis suggests the presence of disequilibrium chemistry, along with a diabatic thermal structure and/or clouds, in the atmosphere of COCONUTS-2b. All models predict fainter $Y$-band fluxes than observed, highlighting uncertainties in the alkali chemistry models and opacities. We determine a bolometric luminosity of $\log{(L{\rm bol}/L_{\odot})}=-6.18$ dex, with a 0.5 dex-wide range of $[-6.43,-5.93]$ dex that accounts for various assumptions of models. Using thermal evolution models, we derive an effective temperature of $T_{\rm eff}=483^{+44}_{-53}$ K, a surface gravity of $\log{(g)}=4.19^{+0.18}_{-0.13}$ dex, a radius of $R=1.11^{+0.03}_{-0.04}$ R${\rm Jup}$, and a mass of $M=8 \pm 2$ M${\rm Jup}$. Various atmospheric model grids consistently indicate that COCONUTS-2b's atmosphere has sub- or near-solar metallicity and C/O. These findings provide valuable insights into COCONUTS-2b's formation history and the potential outward migration to its current wide orbit.