Micro-gap thermo-photo-thermionics: An alternative approach to harvesting thermo-photons and its comparison with thermophotovoltaics (2406.13669v1)

Abstract: This work investigates an alternative to thermophotovoltaics for harvesting thermal and optical energy via photon coupling and thermionic energy conversion. In this device, a heat source is radiatively coupled to a thermionic electron emitter through a nanoscale gap and the electron emitter is coupled to collector through a microscale gap. The analysis using fluctuational electrodynamics and finite time thermodynamics shows that for identical thermal radiator and photon to electron conversion materials, the output power density in the thermionic device can be more than twice that of the thermophotovoltaic device; the thermionic mechanism can also provide more than 30 percent improvement in the energy conversion efficiency compared to the thermophotovoltaic device. Moreover, the maximum power point voltage in the thermionic device is shown to significantly exceed the band gap of conversion material, which determines the theoretical upper limit of the open circuit voltage in a thermophotovoltaic cell. Therefore, the results of this study indicate that thermionic energy harvesting via thermo-photon coupling can be a promising alternative to thermophotovoltaics.