Understanding the degradation of a model Si-anode in Li-ion battery at the atomic-scale (2207.08154v1)

Abstract: Si-anodes have long been candidates thanks to an expected ten-fold increase in capacity compared to graphite. However, details of the mechanisms governing their degradation remain elusive, hindering science-guided development of long-lived Si-based anodes. Here we demonstrate how the latest developments in cryo-atom probe tomography enable the in-depth analysis of the electrode and electrolyte, and their interface at atomic-level.