Temperature dependence and quenching characteristics of (La, Gd)$_2$Si$_2$O$_7$ scintillators at various Ce concentrations (2110.13482v1)

Abstract: We investigated the thermal stability of scintillation and the luminescence performances of (La, Gd)${}{2}$Si${}{2}$O${}{7}$ single crystals at various Ce concentrations. We prepared (La${}{0.25-x}$, Ce${}{x}$, Gd${}{0.75}$)${}{2}$Si${}{2}$O${}{7}$ (x = 0.0001, 0.001, 0.005, 0.01, 0.02, 0.05, and 0.1; unit: molar concentration) single crystals by the Czochralski and micro-pulling-down methods. With increasing Ce concentration, the photoluminescence emission and photoluminescence excitation spectral bands shifted to low energies and the activation energy $\mathrm{\Delta }E$ for thermal quenching decreased. For Ce $\mathrm{<}$ 0.5 at.% samples, the photoluminescence emission background value calculated in the exponential approximation started to increase at temperatures greater than 320 K, which is probably because of Ce${}^{3+}$ 5$\textit{d}$ excited-state ionization. However, the effect was weaker for the Ce $\ge $ 0.5% samples, which may indicate a comparatively larger contribution from other nonradiative relaxations. Thus the main reason for the thermal quenching of the Ce${}^{3+}$ emission in (La, Gd)${}{2}$Si${}{2}$O${}{7}$ is the combination of the 5$\textit{d}$1 excited-state ionization and nonradiative relaxation via thermally excited crossover from the 5$\textit{d}$ excited state to the 4$\textit{f}$ ground state. The temperature dependence of the scintillation light yield was similar irrespective of the Ce concentration, with Ce 1.0% exhibiting the best performance within the temperature range 300 K to 450 K.