Organic Nanodiamonds

Abstract: Nano-crystalline diamond is a new carbon phase with numerous intriguing physical and chemical properties and applications. Small doped nanodiamonds for example do find increased use as novel quantum markers in biomedical applications. However, growing doped nanodiamonds below sizes of 5 nm with controlled composition has been elusive so far. Here we grow nanodiamonds under conditions where diamond-like organic seed molecules do not decompose. This is a key first step toward engineered growth of fluorescent nanodiamonds wherein a custom designed seed molecule can be incorporated at the center of a nanodiamond. By substituting atoms at particular locations in the seed molecule it will be possible to achieve complex multi-atom diamond color centers or even to engineer complete nitrogen-vacancy (NV) quantum registers. Other benefits include the potential to grow ultrasmall nanodiamonds, wherein each diamond no matter how small can have at least one bright and photostable fluorescent emitter.