Emergence of Directed Motion in a Crowded Suspension of Overdamped Particles (2304.12724v1)

Abstract: In this work, we focus on the behavior of a single passive Brownian particle in a suspension of passive particles with short-range repulsive interactions and a larger self-diffusion coefficient. While the forces affecting the single-particle are thermal-like fluctuations and repulsion, due to other particles in the suspension, our numerical simulations show that on intermediate time scales directed motion on a single-particle level emerges. This emergent directional motion leads to a breakdown of the Einstein relation and non-monotonic augmentation of the measured diffusion coefficient. Directional tendency increases with the density of the suspension and leads to growth of the diffusivity with the density of the suspension, a phenomenon recently observed for a system of hard spheres by Ilker, Castellana, and Joanny. Counter-intuitively, the directional flow originates from the tendency of different particles to push each other out of their way. Due to such strictly repulsive interactions, nearby particles form into temporally correlated pairs and move cooperatively, thus creating a preferred direction of motion on intermediate time scales. We show that directional motion emerges when the ratio of the self-diffusion coefficients of the tracked particle and suspension constituents is below a critical value.