A conservative coupling method of sharp-interface and multi-species model for compressible reacting gas-liquid flows with phase change

Abstract: In this paper, a conservative sharp-interface and diffuse-interface coupling method is developed for compressible two-phase multi-species flows with phase change and chemical reactions. The liquid--gas interface is represented by a sharp-interface model, whereas a diffuse-interface model treats the transport and chemical reactions of gas-phase species. Conservation is enforced by coupling the two phases through interfacial fluxes obtained from a multi-species phase-change Riemann problem. The original single-species four-wave Riemann solver is extended to multi-species gas mixtures by modifying the interfacial energy jump condition. Interfacial mass transfer is restricted to the condensable vapor species. Accordingly, both the interfacial energy jump condition and the gas-mixture energy-exchange flux are constructed using the internal energy of the phase-changing vapor species rather than the mixture internal energy. With this species-selective energy coupling, an approximate multi-species Riemann solver is constructed that retains the four-wave structure while avoiding the multidimensional nonlinear root-finding required by the exact solution. A series of numerical tests, including impulsive evaporation and condensation, reacting aluminum vaporization, shock-droplet interaction, and detonation-droplet interaction, are performed to assess the accuracy and robustness of the method. The numerical results agree well with reference solutions and benchmark data, demonstrating that the present method resolves the effects of phase change and chemical reactions in compressible multi-species multiphase flows while preserving conservative interfacial coupling.