Electronic reconstruction and interface engineering of emergent spin fluctuations in compressively strained La$_3$Ni$_2$O$_7$ on SrLaAlO$_4$(001)

Abstract: Motivated by the recent observation of ambient-pressure superconductivity with $T_c \sim 40$ K in La3Ni2O7 on SrLaAlO4(001) (SLAO), we explore the structural and electronic properties as well as the spin-spin correlation function of this bilayer nickelate system by using density functional theory including a Coulomb repulsion term. We find that the compressive strain exerted by this substrate leads to an unconventional occupation of the antibonding Ni $3d_{z^2}$ states, distinct from the superconducting bulk compound under pressure. While pure strain effects rather modestly enhance the dynamical spin susceptibility via Fermi surface nesting, investigation of a reconstructed interface composition as observed in transmission electron microscopy uncovers a strong amplification of the spin fluctuations. These results provide insights into the emergence of superconductivity in strained La$_3$Ni$_2$O$_7$, suggest a possible key role of the interface, and highlight fundamental differences from the hydrostatic pressure scenario.