Emergence of cross-layer composite spins in La$_4$Ni$_3$O$_{10}$ under pressure and possible routes to enhance its superconductivity

Abstract: Trilayer La$4$Ni$_3$O${10}$ has been recently found to exhibit superconductivity in its high-pressure phase, similar to the previously discovered bilayer La$3$Ni$_2$O$_7$, but with a notably lower transition temperature. To date the pressure effects on the electronic correlations beneficial for unconventional superconductivity remains unclear, as well as the potential similarities or differences compared to the bilayer La$_3$Ni$_2$O$_7$. We use a multi-energy-scale derivation of the inter-layer electron dynamics to identify the dominant emergent spin-charge correlations in trilayer La$_4$Ni$_3$O${10}$. Similar to the bilayer La$3$Ni$_2$O$_7$, we find fractionalization of ionic spins in the high-pressure phase that results in cuprate-like spin-$\frac{1}{2}$ ions correlated with itinerant carriers. This suggests a similar superconducting mechanism in other nickelate and cuprate superconductors. Interestingly, extra composite spins emerge as cross-layer trimers in the trilayer system, whose suppression of ionic spin fluctuations naturally explains the weaker superconductivity observed in La$_4$Ni$_3$O${10}$, and indicates that lowering layer symmetry is a viable strategy to improve superconductivity in this trilayer nickelate.