A comparison between the FENE-P and sPTT constitutive models in Large Amplitude Oscillatory Shear (LAOS)

Abstract: The FENE-P and sPTT viscoelastic models are widely used for modelling of complex fluids. Although they are derived from distinct micro-structural theories, these models can become mathematically identical in steady and homogeneous flows with a particular choice of the value of the model parameters. However, even with this choice of parameter values, the model responses are known to differ from each other in transient flows. In this work, we investigate the responses of the FENE-P and sPTT constitutive models in Large Amplitude Oscillatory Shear (LAOS). In steady-shear, the shear stress scales with the non-dimensional group $Wi/(aL) \ (Wi\sqrt{\epsilon})$ for the FENE-P (sPTT) model, where $Wi$ is the Weissenberg number, $L^2$ is the limit of extensibility in the FENE-P model ($a$ being $L^2/(L^2-3)$) and $\epsilon$ is the extensibility parameter in the sPTT model. Our numerical and analytical results show that, in LAOS, the FENE-P model only shows this universality for large values of $L^2$ whereas the sPTT model shows this universality for all values of$\epsilon$. In the strongly non-linear region, there is a drastic difference between the responses of the two models, with the FENE-P model exhibiting strong shear stress overshoots which manifest as self-intersecting secondary loops in the viscous Lissajous curves. We quantify the non-linearity exhibited by each constitutive model using the Sequence of Physical Processes framework. Despite the high degree of non-linearity exhibited by the FENE-P model, we also show using fully non-linear 1D simulations that it does not shear band in LAOS within the range of conditions studied.