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Sufficiency of Martian electron acceptors for atmospheric O2 buildup

Determine whether Mars contains a sufficient inventory of electron acceptors—specifically carbon, ferric iron, and sulfate—to sequester hydrogen derived from water so that oxygen can accumulate to form the oxygen-rich atmosphere envisioned for a terraformed Mars.

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Background

In the proposed terraforming pathway, a long-term oxygen-rich atmosphere would be produced by photosynthesis and sustained only if the corresponding hydrogen from water is effectively sequestered. On Earth, analogous sinks include burial of reduced carbon and reactions with oxidized minerals.

The document flags this as a Potential Showstopper because if Mars lacks adequate electron acceptors, produced oxygen would not accumulate as intended, fundamentally challenging the feasibility of achieving the envisioned oxygen atmosphere.

References

Oxygen build-up in the atmosphere implies that hydrogen from water is sequestered (analogous to organic-matter burial from Earth). We do not know if Mars contains enough electron acceptors (carbon, ferric iron, sulfate) to serve as a hydrogen sink and liberate the necessary amount of oxygen from water for the desired atmosphere.

An Introduction to Mars Terraforming, 2025 Workshop Summary (2510.07344 - Stork et al., 7 Oct 2025) in Section “What is different about a Green Mars?”, Key unknowns and research priorities (Potential Showstopper)