Global proof of monotonicity for the Abrikosov–Gor'kov scaling function
Prove that \(h'(x)=\psi'(x)+(x-\tfrac12)\psi''(x)>0\) for every \(x>1\), thereby establishing analytically the global monotonicity of the Abrikosov–Gor'kov scaling function and rigorously validating the necessary-and-sufficient crossing criterion.
References
For large x the Stirling expansion gives h'(x)=1/(6x{3})+O(x{-4})>0. In the intermediate range we verify Eq.~eq:hprime numerically (h'=0.443,\, 3.88\times10{-2},\, 1.77\times10{-3},\,1.37\times10{-6} at x=1,2,5,50; positive on a 2\times10{5}-point scan of x\in[\tfrac12+10{-4},500], with h'\sim1/(6x3)>0 controlling x>500), but we have not found a closed-form proof of positivity for all x>1. Accordingly we state Eq.~eq:crosscrit as necessary and sufficient given the monotonicity of the AG scaling function established analytically at both ends of the interval and verified numerically in between---not as a fully proved ``if and only if.''