When voltage sensors fail: Electrochemically constrained fault-tolerant state estimation for flat-plateau LFP batteries

Abstract: The flat voltage plateau of lithium iron phosphate (LFP)/graphite cells makes electrochemical-state errors and voltage-measurement abnormalities produce similar innovations, complicating state-of-charge (SOC) estimation. This work proposes an electrochemically constrained residual-bias compensation dual extended Kalman filter (RBC-DEKF) with uncertain-initialization commissioning. A thermal control-oriented parameter-grouped single-particle model (CPG-SPMT) provides paired-electrode dynamics and terminal-voltage prediction, while a separately configurable voltage-discrepancy state accommodates systematic residuals. When the initial SOC is uncertain, residual adaptation is suspended over a verified-healthy startup window. Buffered data support electrochemically constrained trajectory matching, followed by calibrated state replay and residual-channel reactivation. Frozen cross-cycle healthy-residual calibration supports commissioning and remains in the voltage prediction after handover. Evaluation covers 216 additive-bias and 168 multiplicative-gain profiles over 24 A123 temperature-drive-cycle trajectories. Relative to Single-EKF, the original RBC-DEKF reduces mean SOC RMSE from 7.646 to 0.170 percentage points for additive bias and from 22.646 to 0.356 percentage points for gain faults. Separately, 18 nonzero-initial-error profiles on three representative 50%-SOC-anchored segments give a full-record mean SOC RMSE of 1.747 percentage points, including startup, for the commissioned realization, versus 11.192 and 11.400 for the always-on RBC-DEKF and conventional joint EKF. Representative delayed bias, 10-s ramp, and gain tests show that the corrected SOC trajectory remains stable after fault introduction. The central contribution is electrochemically constrained temporal coordination of uncertain-state recovery and subsequent voltage-discrepancy accommodation.