Predicting the Elastic Properties of a Cemented Granular Material during Chemical Damage (Debonding)

Abstract: While underground reservoirs emerge as essential elements to face global warming, these systems represent complex multi-physical and multiscale problems. The considered injection of fluids during hydrogen storage, carbon dioxide sequestration, or geothermal energy recovery involves a modification of the chemical equilibrium of the fluid in the porous reservoir. Chemical reactions can induce microstructural changes of the rock matrix, leading to a reduction of elastic properties of the material, and to potential settlement or stress redistribution. Consequently, it becomes pivotal to establish predictive behavior laws to describe the effect of chemical damage on elastic properties. Facing the difficulties to estimate experimentally the impact of chemical damage on mechanical properties, a Digital Rock Physics approach is proposed in this contribution. This numerical homogenization scheme is used to compare two distinct types of microstructure models: the first one consists in a Discrete Element Model, while the second one employs a continuous description. This continuous formulation is based on a Phase-Field description to predict the evolution of the microstructure subjected to chemical alterations and on the Fast Fourier Transform to estimate the macroscopic properties of the material. Finally, these frameworks establish different softening laws that can be used as constitutive ingredients for a cemented material during its weathering.