Disordered ground states in one-dimensional exactly solvable fluids
Abstract: One-dimensional fluids of classical hard-core particles of diameter , interacting in pairs via a soft repulsive (monotonically decreasing) potential of finite range $\varphi(x)=\varepsilon \left[ (a'-x)/(a'-a)\right]<sup>{1/ν}$ $(a\le x\le a')$ with real positive parameters and , are studied in an isothermal-isobaric ensemble. If $a'\le 2a$, the pairwise interactions are reduced to nearest-neighbour interactions, which allows for an exact solution of the thermal equilibrium. We focus on the ground states, specifically on the equation of state for the mean distance between nearest neighbours and the pair correlation function . If is concave , there exists an ``incompressibility'' pressure $p_i=\varepsilon/(a'-a)$ such that the ground state is an equidistant chain of particles with spacing $l_0=a'$ for $0<p<p_i$ and with spacing for $p>p_i$. If $ν>1$ (strict concavity), the ground state at is disordered with $l_0=\left[ νa +(ν-1)a'\right]/(2ν-1)$ and being a superposition of weighted Dirac delta functions over discrete positions. If (linear ramp), the ground state at is disordered with $l_0=(a+a')/2$ and the continuous is a superposition of Heaviside step functions multiplied by polynomials in . The isothermal susceptibility at is nonzero for concave () at and, therefore, the corresponding disordered ground states are non-hyperuniform, i.e., they resemble disordered fluids at nonzero temperatures. It turns out that pair correlation functions of disordered ground states, which occur only at a single pressure , extend their predictive power to thermodynamic states at nonzero temperatures over a wider range of pressures around .
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