JWST-SUPER I: New insights into irradiated warm Neptunes atmospheres from MIRI observations of HD 106315 c

Abstract: Sulphur-bearing molecules have recently emerged as powerful tracers of atmospheric photochemistry in exoplanets observed with JWST. In several warm giant planets, SO$<em>2$ has been detected as a product of UV-driven chemical processing, suggesting a close connection between stellar irradiation, atmospheric metallicity, and sulphur chemistry. Whether these trends extend to Neptune-mass planets orbiting hotter stars remains largely unexplored. We investigate the atmospheric composition of the warm Neptune HD 106315 c, a Neptune-mass planet orbiting an F-type host star and subjected to a strong ultraviolet (UV) irradiation environment. Here, we report the low-resolution transmission spectrum between 5 and 12 $μ$m of HD 106315 c obtained with the MIRI Low-Resolution Spectrometer on-board JWST. Our work also includes re-analysis of archival data from HST WFC3 G141 mode of HD 106315 c, as well as contemporaneous XMM and Swift monitoring of the star in the UV and X-ray wavelength ranges. Together with the archival HST WFC3 data, we detect H$_2$O and find tentative evidence for NH$_3$, retrieving abundances of $\log</em>{10}$(H$<em>2$O)$=-1.40^{+0.40}</em>{-0.74}$ and $\log_{10}$(NH$<em>3$)$=-2.47^{+0.57}</em>{-0.89}$, together with an isothermal terminator temperature of $747<sup>{+150}_{-155}$ K. We place stringent upper limits on CH$_4$, SO$_2$, and CS$_2$, finding no robust evidence for any sulphur-bearing species despite the intense irradiation received by the planet. The inferred water abundance implies a strongly metal-enriched atmosphere. Elevated intrinsic temperatures can reconcile the non-detections of CH$_4$ and CS$_2$ through carbon--sulphur coupling, while the absence of SO$_2$ points toward a reduced atmospheric sulphur inventory or a near-solar to mildly enhanced C/O ratio, and places HD 106315 c near the transition between sulphur-rich and sulphur-poor chemical regimes.