Quantum Noncommutativity Uniquely Determines Relative Entropy

Abstract: Quantum relative entropy is a core concept in physics, governing the limits of communication, thermodynamic irreversibility and quantum resource conversion. However, the requirement that physical processes cannot increase state distinguishability, the data-processing inequality, permits an infinite family of alternative divergence measures. Here we show that quantum relative entropy is uniquely selected by a sharper operational principle. We evaluate distinguishability through binary guessing games, in which an observer discriminates between pairs of quantum states using the optimal measurement. We prove that any additive measure that respects the odds revealed by these optimal measurements must coincide with the Umegaki relative entropy. This rigidity is a purely quantum phenomenon. Whereas classical theory permits a continuous family of valid divergence measures, including Rényi divergences, quantum noncommutativity. collapses this mathematical freedom. The result is exact, requiring neither a thermodynamic limit of infinitely many copies nor super-additivity assumptions for correlated states. It establishes quantum relative entropy not merely as an asymptotic quantity, but as the unique additive distinguishability measure compatible with single-shot quantum discrimination.