Rapid and robust parameter estimation for electrochemical battery models via BOLT: A batch-optimized local-to-global technique

Abstract: Accurate and efficient parameter estimation is essential for applying electrochemical battery models in simulation, state estimation, control, and repeated model updating. However, conventional optimization methods, such as particle swarm optimization (PSO) and genetic algorithms (GA), often require many model evaluations and show considerable run-to-run variability, limiting their use in time-sensitive calibration scenarios. This study proposes a Batch-Optimized Local-to-Global Technique (BOLT) for rapid and robust parameter estimation of electrochemical battery models. BOLT combines diversified candidate initialization, batch-parallel trust-region reflective (TRF) local refinement, JIT-accelerated model evaluation, and multi-condition consistency screening within a unified calibration workflow. Comparative experiments based on a grouped single-particle model and measured data from a commercial 18650 NMC lithium-ion cell show that BOLT achieves a favorable trade-off among voltage-response accuracy, computational efficiency, and repeated-run stability. BOLT(32) achieves an average mean absolute error of (12.4 \pm 0.1) mV over five operating conditions, requiring only (20636 \pm 3081) model calls and (8.97 \pm 1.20) s per run. Synthetic-data validation with a known parameter vector in the grouped SPM formulation further shows that BOLT recovers the reference parameter vector under model-consistent conditions and remains robust under 1--3 mV voltage-noise perturbations, with the mean parameter absolute relative error below (0.6\%). These results indicate that BOLT provides a practical calibration framework for BMS parameter updating, control-oriented battery digital twins, and second-life battery screening.