Universality of Bubble Coalescence in Electrolytic Media

Abstract: Bubble coalescence phenomenon in electrolytic media finds applications in technologies from mineral flotation to electrochemical energy conversion. However, the underlying governing physics still remains unresolved, with longstanding disagreement over the extent to which Marangoni stresses affect the coalescence time by modulating the interfacial mobility. Here, we show that the thin film morphology governs drainage more strongly than the interfacial boundary conditions. We demonstrate experimentally that thin film drainage during bubble coalescence proceeds through three distinct regimes. An initial visco-capillary stage that exhibits a power-law thinning, followed by an exponential decrease in film thickness with time induced by rim stabilisation. The final regime is governed by disjoining pressure and is marked by an exponential relaxation of the film to the equilibrium thickness. We show that, irrespective of the electrolyte type and concentration, film evolution exhibits universal behavior by collapsing onto a single curve when rescaled with the characteristic film thickness and time scale, demonstrating that electrolyte effects act only to renormalize timescales rather than alter the underlying dynamics.