Symmetry-Selective Strain Control of Spin-Momentum Locking and Spin Transport in Two-Dimensional Pentagonal Altermagnets

Abstract: Altermagnets are compensated magnets featuring momentum-dependent nonrelativistic spin splitting generated by nontrivial operations connecting opposite-spin sublattices. A direct symmetry-based route to control this spin splitting is to modify the real-space operations that define the altermagnetic spin-momentum locking (SML). Here, we develop a strain-resolved symmetry framework for two-dimensional pentagonal altermagnets, classifying whether uniaxial and shear strain tensors preserve, reconstruct, or eliminate the SML. Using the above criterion combined with first-principles screening, we identify 94 stable altermagnetic candidates from 3330 materials. These candidates cover all type-III spin Laue groups of orthorhombic lattices and are classified into three strain-response types: Type-I preserves the SML; Type-II reconstructs the SML through partial symmetry breaking while retaining essential altermagnetic features; and Type-III destroys the altermagnetic SML. Representative materials further demonstrate this classification: ferroelastic $α$-CoS$_2$ exhibits ferroelastically switchable SML and reverses the sign of the off-diagonal spin conductivity; shear-strained (α)-CoP(_2) undergoes a (g)- to (d)-wave reconstruction of the SML, activating off-diagonal spin conductivity; and uniaxially strained FeSSe realizes strain-selected spin-valley transport. This work provides theoretical and material guidance for strain-controlled transport in two-dimensional orthorhombic altermagnets.