Evidence for Multiband Superconductivity in 2H-NbSeS

Abstract: The nature of superconductivity in 2H-NbSe2 has generated sustained debate in the recent past. While angle resolved photoemission spectroscopy data have been interpreted as evidence for multiband superconductivity, the data from scanning tunneling microscope experiments relate to strongly anisotropic single-band superconductivity. In the later case, the charge density wave (CDW) order mimics the multigap character. Because the CDW reconstructs the Fermi surface and modifies the superconducting gap distribution, disentangling intrinsic multiband pairing from CDW-related effects is challenging. To address this issue, we investigate single-crystalline 2H-NbSeS, a mixed-chalcogen analogue of 2H-NbSe2 in which random Se/S substitution suppresses long-range CDW order while preserving the layered crystal structure P63/mmc. The material becomes superconducting below 6.0 K with moderate magnetic anisotropy. The upper critical field exhibits a pronounced upward curvature that cannot be described within a single-band framework but is well captured by a dirty-limit two-band model with a large diffusivity ratio. This indicates strong band-dependent scattering. The in-plane upper critical field exceeds the weak-coupling Pauli limit. Measurements of the lower critical field, superfluid density, and electronic specific heat are consistent with an interpretation of a fully gapped superconducting state with two nodeless gaps of different magnitudes.