Abstract: In this paper, we mainly investigate zero-sum problems over Z/nZ (with $n>1$) of two new types. Let s1​(n) (resp. t1​(n)) be the least positive integer k such that for any integers a1​,…,ak​ not divisible by n (resp., relatively prime to n), there is an I⊆1,…,k with ∣I∣=n for which the sum ∑i∈I​ai​ is divisible by n but not divisible by n<sup>2. For n⩾4, we prove that 2n+1⩽s1​(n)⩽n<sup>2−2n+2 and 2n−(−1)<sup>n⩽</sup>t1​(n)⩽(n−1)φ(n)+1. We conjecture that s1​(n)=2n+1 and t1​(n)=2n−(−1)<sup>n for any integer $n>2$.