Temperature-programmed desorption of SO2 from water ice surfaces: Adsorption energy distributions

Abstract: Context. Sulphur-bearing species play a key role in the chemical evolution of the interstellar medium and icy Solar System bodies such as the Jovian moons, yet the sulphur budget remains poorly constrained. Sulphur dioxide is considered one of the main sulphur reservoirs in icy environments, making its interaction with water ice surfaces highly relevant for astrochemical models. Aims. This work aims to extract adsorption energy distributions of SO2 on water ice substrates as a relevant model for astrophysical environments to better constrain its thermal behaviour and solid-gas exchange for astrochemical simulations. Methods. We performed a systematic experimental study of temperature-programmed desorption of SO2 deposited on three types of surfaces -- polycrystalline gold, compact amorphous solid water (c-ASW), and crystalline water under ultra-high vacuum conditions -- to then extract, using a Polanyi-Wigner model, the adsorption energy distributions of SO2 on each surface. Results. We performed the extraction of the adsorption energy distribution of SO2 deposited on water ice substrates. These exhibit a bimodal structure: a first physisorbed layer and a second, more strongly bound population. Only minor differences are observed between c-ASW and crystalline water ice in the behaviour of the distributions. We also provide mean values, most probable values, and width of the distribution. On average, the binding energy of SO2 on water ice surface is 439 +- 41 meV.