XRISM spectroscopy of a crowded Galactic center region -- III. S, Ar and Ca ISM Absorption Features in the spectrum of MAXI J1744-294

Abstract: We present a comprehensive study of X-ray absorption by sulfur (S), argon (Ar), and calcium (Ca) in the interstellar medium (ISM) along the line of sight to the low-mass X-ray binary MAXI J1744$-$294, using high-resolution XRISM Resolve spectra complemented by Chandra HETG data. The analysis employs an updated ISMabs model, incorporating newly computed $R$-matrix photoabsorption cross-sections for Ca I$-$Ca III, and existing cross-sections for higher ionization states. We find that S and Ar are predominantly in low-ionization states, with S II and Ar II dominating the cold and warm ISM phases, while higher-ionization species are constrained by upper limits. Calcium is primarily detected in low-ionization states, consistent with strong depletion into dust grains, with only marginal contributions from highly ionized ions. Using the measured ionic column densities, we infer hydrogen column densities of $N_{\rm H} \sim 1.1$-$1.3 \times 10<sup>{23}\,\mathrm{cm<sup>{-2}}$ from S and Ar, while the Ca-based value, tracing the neutral ISM, is in agreement with these estimates, highlighting the consistency across different tracers. Our results demonstrate the diagnostic power of combining multiple elements to probe ISM ionization structure, elemental depletion, and dust composition, and provide the first X-ray constraints on calcium absorption in the interstellar medium.