Macroscopic Mpemba Effect from Cumulative-Heat-Enhanced Relaxation

Abstract: The counterintuitive Mpemba effect, wherein a hotter system cools faster, critically lacks a universal macroscopic theory. Here, starting from linear irreversible thermodynamics, we formulate a generalized Newton's cooling law for the system-reservoir temperature difference $ΔT$, given by $\mathrm{d}ΔT/\mathrm{d}t = -[γ_0 + \mathcal{M}Q(t)][ΔT - \mathcal{I}Q(t)]$, where $γ_0$ is the bare relaxation rate, and the cumulative heat exchange $Q(t)$ explicitly encodes initial-state memory. The coefficients $\mathcal{M}$ and $\mathcal{I}$, arising from the interplay between heat flux and structural evolution, govern diverse anomalous relaxation behaviors. Specifically, $\mathcal{M} > 0$ ($\mathcal{M} < 0$) induces the (inverse) Mpemba effect, while $\mathcal{I}$ imposes a non-vanishing asymptotic $ΔT$, predicting incomplete thermalization. Our findings capture the full spectrum of memory-dependent relaxation, bridging kinetic speedup with structural freezing in complex systems.