Passive Daytime Radiative Cooling Enabled by Bio-Derived Ceramic-Polymer Coatings on Rapid-Curing Fiberglass Casts

Abstract: Passive daytime radiative cooling (PDRC) provides an energy-free approach to suppress surface temperatures by reflecting solar irradiation while emitting thermal radiation through the mid-infrared atmospheric window. Despite rapid progress in optical performance, most PDRC systems remain limited by rigid, fragile, or planar substrates, restricting their use on flexible, curved, or wearable surfaces. Here, we report a biocompatible and structurally robust PDRC system integrated onto a commercial rapid-curing fiberglass cast, a conformal substrate widely used in orthopedic and industrial applications. The cooling architecture adopts a bilayer polymer design consisting of a polyvinyl alcohol (PVA) adhesion layer and a polymethyl methacrylate (PMMA) protective layer, both embedded with calcium pyrophosphate (CPP) ceramic particles derived from processed animal bone waste. The bio-derived CPP simultaneously enables broadband solar scattering and high mid-infrared emittance, while offering sustainability and biocompatibility advantages. The resulting composite exhibits over 90% solar reflectance and achieves up to 15 C sub-ambient cooling under direct outdoor sunlight.