Microscopic origin of orbital magnetization in chiral superconductors

Abstract: Chiral superconductivity is a time reversal symmetry breaking superconducting phase that has attracted broad interest as a potential platform for topological quantum computation. A fundamental consequence of this symmetry breaking is orbital magnetization, yet a clear microscopic formulation of this quantity has remained elusive. This difficulty arises because Bogoliubov quasiparticles do not carry a definite electric charge, precluding a simple interpretation of orbital magnetization in terms of circulating quasiparticle currents. Moreover, superconductivity and ferromagnetism rarely coexist, and in the few materials where they do (e.g. uranium-based compounds), strong spin-orbit coupling obscures the orbital contribution to the magnetization. The recent report of chiral superconductivity in rhombohedral multilayer graphene, which has negligible spin-orbit coupling, therefore provides a unique opportunity to develop and test a microscopic theory of orbital magnetization in chiral superconductors. Here we develop such a theory, unifying the interband coherence effects underlying normal-state orbital magnetization with the intrinsic orbital moments of the Cooper-pair condensate. Applying our theory to rhombohedral tetralayer graphene, we find that the onset of superconductivity can either enhance or suppress the normal-state orbital magnetization, depending sensitively on the bandstructure. We further identify a generalized clapping mode corresponding to coherent fluctuations between the two opposite chiral windings of the p-wave order parameter, with a gap set by the sublattice winding form factor. This collective mode is unique to chiral superconductors and contributes to the orbital magnetization through its role in dressing the photon vertex. Experimental measurements of the orbital magnetization relative to the quarter-metal phase would provide a direct test of our theory.