The atmospheric composition of TOI-270 d

Abstract: The first explorations of temperate sub-Neptune exoplanets have been the hallmark of early JWST observations. The bulk properties of such planets are consistent with a range of possible internal structures, which can be distinguished through their interactions with the observable atmospheres. JWST observations of TOI-270 d, a temperate sub-Neptune, have previously led to contrasting conclusions: either a Hycean world, possessing a liquid water ocean, or a mixed-envelope sub-Neptune, where high temperatures prevent a liquid ocean and lead to a high mean molecular weight atmosphere. In order to resolve this uncertainty, we present a comprehensive retrieval analysis of TOI-270 d using recent NIRISS and NIRSpec transit spectroscopy across $\sim$1-5 $μ$m. We find that prior inferences of a mixed envelope were affected by specific modelling choices leading to a high terminator temperature and high mean-molecular weight in the atmosphere. We confirm an H$<em>2$-rich atmosphere in TOI-270 d and present revised constraints on the molecular log-mixing ratios and maximal detection significances of CH$_4$ at $-1.86^{+0.30}</em>{-0.29}$ (6.4 $σ$), CO$<em>2$ at $-1.71^{+0.38}</em>{-0.66}$ (3.9 $σ$), H$<em>2$O at $-1.88^{+0.78}</em>{-4.13}$ (2.1 $σ$) and CS$<em>2$ at $-4.74^{+0.65}</em>{-1.10}$ (2.0 $σ$), with a terminator temperature of $323<sup>{+58}_{-52}$ K at 10 mbar. We also find tentative evidence for more complex methyl-bearing species such as C$_2$H$_6$ and/or DMS at a 2.1-2.5 $σ$ level. The present constraints are consistent with TOI-270 d being a Hycean or dark Hycean world, with planet-wide or nightside liquid water oceans. However, more observations are required to verify the present findings and robustly constrain the atmospheric conditions and internal structure of TOI-270 d.