Generalized Boundary Conditions for the qBounce Experiment

Abstract: Discrepancies between theory and recent qBounce data have prompted renewed scrutiny of how boundary conditions are implemented for ultracold neutrons bouncing above a mirror in Earth's gravity. We apply the theory of self-adjoint extensions to the linear gravitational potential on the half-line and derive the most general boundary condition that renders the Hamiltonian self-adjoint. This introduces a single real self-adjoint parameter $\lambda$ that continuously interpolates between the Dirichlet case and more general (Robin-type) reflecting surfaces. Building on this framework, we provide analytical expressions for the energy spectrum, eigenfunctions, relevant matrix elements, and a set of sum rules valid for arbitrary $\lambda$. We show how nontrivial boundary conditions can bias measurements of $g$ and can mimic or mask putative short-range ''fifth-force''. Our results emphasize that enforcing self-adjointness-and modeling the correct boundary physics-is essential for quantitative predictions in gravitational quantum states. Beyond neutron quantum bounces, the approach is broadly applicable to systems where boundaries and self-adjointness govern the observable spectra and dynamics.