Evolution of the superconductivity in pressurized La3-xSmxNi2O7

Abstract: Motivated by the discovery of superconductivity in bilayer La$<em>3$Ni$_2$O$_7$ at 80 K and the increased superconducting transition temperature, $T</em>\text{c}$, up to 92 K in single crystals of La$<em>2$SmNi$_2$O$_7$ under pressure, we systematically study the effect of Sm doping on the superconductivity and structure of La$</em>{3-x}$Sm$<em>x$Ni$_2$O$_7$ (0 $\leq$ x $\leq$ 1.5) under pressure. Experimental investigations in polycrystalline samples reveal that Sm doping monotonically decreases the lattice constants $c$ and $a$, thereby enhancing crystal structure distortion and leading to an evolution of the metallic ground state in La$_3$Ni$_2$O$_7$ to an insulating state in La$</em>{1.5}$Sm$<em>{1.5}$Ni$_2$O$_7$. The maximum onset $T</em>\text{c}$ in compounds $x=0.9$ and 1.5 is 89 K, while the pressure that drives the emergence of superconductivity is higher for higher doping levels. The results suggest that the enhancement of $T_\text{c}$ in La$_{3-x}$Sm$_x$Ni$_2$O$_7$ is mainly affected by the compressed $c$ lattice before saturation, and the structure transition is critical for the emergence of superconductivity. Our experimental results provide insight into the influence of elemental substitution on nickelate superconductors, offering a means to increase the transition temperature further.