Thermodynamic analysis of water sorption isotherms on magnetically treated maize (Zea mays L.) seeds

Abstract: Magnetic seed treatment (MST) is an effective technique for improving conditions in processes associated with germination, stability, and, ultimately, crop production. In this work, the technical management parameters related to the water adsorption process on magnetically treated Zea mays L. seeds will be determined. Models were compared to describe the experimentally obtained adsorption isotherms using nonlinear regressions. The modeling parameters, along with the Clausyus-Clapeyron equation, were used to determine the differential enthalpy, differential entropy, and Gibbs free energy present in the process. In addition, the compensation theory for this system was validated. The results indicate an overall reduction in the energy required to establish equilibrium in the water-seed system as the moisture content increases. A relationship is observed that will inject Gibbs free energy into the system at the extremes of the magnetic dose applied to the seeds. This relationship is stable as a first approximation to understand the energetic aspects when connecting the magnetic processing of seeds.