Many-Body Rashba Spin-Orbit Interaction and Exciton Spin Relaxation in Atomically Thin Semiconductor Structures

Abstract: We propose a previously unexplored spin-orbit interaction mechanism by establishing a mesoscopic many-particle Rashba Hamiltonian. In lowest order, this Hamiltonian self-consistently describes exciton spin relaxation in monolayer transition metal dichalcogenides (TMDC) due to local electric fields caused by spatial asymmetries in the dielectric environment. For a monolayer MoSe$_2$ on a SiO$_2$ substrate above 77\,K showing a meV bright-dark splitting, the local electric field causes fast intravalley spin relaxation on a sub-picosecond timescale, whereas it is negligible for other TMDCs with larger bright-dark splitting.