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Variational studies of ro-vibrational spectra of DT$^+$ and T$_2^+$ ions

Published 16 Jul 2025 in physics.atom-ph | (2507.12243v1)

Abstract: In this work we study the last two hydrogen molecular ion isotopologues: DT$+$ and T$_2+$, for which high-precision calculations have not yet been made. We obtain the nonrelativistic solutions of the Schr\"odinger equation for the wide range of vibrational states up to the highest possible vibrational $1s\sigma_g$ state which are of spectroscopic precision. Transition amplitudes for electric dipole transitions, leading-order relativistic corrections and coefficients of the effective hyperfine structure Hamiltonians for both DT$+$ and T$_2+$ are also calculated.

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