Lack-of-fit reduction in the path-integral formalism (2506.20242v1)

Abstract: We present a reformulation of the lack-of-fit reduction in non-equilibrium thermodynamics using the path-integral formalism. The reformulation is based on the Onsager-Machlup variational principle, and it allows us to minimize the action while keeping only thermodynamically relevant solutions. The reduced evolution consists of a Hamiltonian vector field and a gradient flow. The reformulation is illustrated on the Kac-Zwanzig model, where we show how irreversibility emerges from purely Hamiltonian evolution by ignoring some degrees of freedom. We also show how to generalize the Fisher information matrix and Kullback-Leibler divergence between two probability distributions to the case when the two distributions are related by the principle of maximum entropy, even in the case when the entropy is not of Boltzmann-Gibbs type (for instance Tsallis-Havrda-Charvat).