Tailoring the breathing-mode distortions in nickelate-ferroelectric heterostructures

Abstract: In transition metal oxides electron-electron interaction and lattice degree of freedom are basic ingredients of emergent phenomena, such as metal-to-insulator transition (MIT) and superconductivity. Perovskite rare-earth nickelates are largely studied for their temperature-driven MIT which is accompanied by a breathing mode distortion, and associated to a bond-disproportionation of the expanded (3d8L0) and compressed (3d8L2) NiO6 octahedra. Steric effects control the onset temperature of the MIT, the latter being concomitant or not with a complex antiferromagnetic spin arrangement depending upon the choice of the rare earth ion (TMIT>TNeel). Interface engineering of oxygen octahedra tilting, as imposed by the symmetry and orientation of the substrate, has resulted in an efficient pathway to modify both TMIT and TNeel, hence, suggesting a key role of the electron-phonon coupling for both transport and magnetic properties in nickelate thin films. Here, via a combination of resonant elastic X-ray scattering and transport experiments, we show a control over both TMIT and TNeel in heteroepitaxial PZT(d)/NNO(7 nm)//STO heterostructures, which are characterized by different strains and polarization states of the PZT layer grown at different thicknesses d. We found the expected NNO bulk behaviour, for a fully relaxed PZT layer showing a monodomain polarization state. On the other side, an almost 30 K difference, is found for a fully strained PZT characterized by a multidomain texture of the polarization state. We discuss our results in terms of an altered breathing distortion pattern of the underlying nickelate layer as supported by X-ray absorption spectroscopy measurements. We infer that locally different polar distortions controlled by a combination of polarization direction and strength of the strain state play the main role in the observed TMIT and TNeel variations.