Thermodynamics of driven systems with explicitly broken detailed balance (2501.12192v1)

Abstract: In systems with detailed balance, the stationary distribution and the equilibrium distribution are identical, creating a clear connection between energetic and entropic quantities. Many driven systems violate detailed balance and still pose a challenge for a consistent thermodynamic interpretation. Even steady-state potentials like entropy or free energy are no longer state variables. Here, we use a framework for systems with broken detailed balance, where Boltzmann entropy can be computed while properly taking constraints on state transitions into account. As an illustration, we establish the thermodynamic relations for arbitrarily driven sample space-reducing processes that are non-equilibrium but show steady states. We demonstrate that, despite explicitly broken detailed balance, it remains feasible to define and unambiguously interpret the effective thermodynamic potentials.