Spin-Degenerate Bulk Bands and Topological Surface States of RuO2

Abstract: Altermagnets are a novel platform to realize exotic electromagnetic properties distinct from those of conventional ferromagnets and antiferromagnets. We report results of micro-focused angle-resolved photoemission spectroscopy (ARPES) on RuO2, of which altermagnetic nature has been under fierce debate. We have elucidated the band structure of the (100), (110) and (101) surfaces of a bulk single crystal. We found that, irrespective of the surface orientation, the experimental band structures obtained by ARPES commonly show a semi-quantitative agreement with the bulk-band calculation for the nonmagnetic phase, but display a severe disagreement with that for the antiferromagnetic phase. Moreover, spin-resolved ARPES signifies a negligible spin polarization for the bulk bands. These results suggest the absence of antiferromagnetism and altermagnetic spin splitting. Furthermore, we identified a flat surface band and a dispersive one near the Fermi level at the (100)/(110) and (101) surfaces, respectively, both of which are attributed to the topological surface states associated with the bulk Dirac nodal lines. The present ARPES results suggest that the crystal-orientation-dependent topological surface/interface states need to be taken into account to properly capture the transport and catalytic characteristics of RuO2.