Why gauge invariance applies to statistical mechanics (2409.14166v3)

Abstract: We give an introductory account of the recently identified gauge invariance of the equilibrium statistical mechanics of classical many-body systems [J. M\"uller et al., Phys. Rev. Lett. Phys. Rev. Lett. 133, 217101 (2024)]. The gauge transformation is a non-commutative shifting operation on phase space that keeps the differential phase space volume element and hence the Gibbs integration measure conserved. When thermally averaged any observable is an invariant, including thermodynamic and structural quantities. Shifting transformations are canonical in the sense of classical mechanics. They also form an infinite-dimensional group with generators of infinitesimal transformations that build a non-commutative Lie algebra. We lay out the connections with the underlying geometry of coordinate displacement and with Noether's theorem. Spatial localization of the shifting yields differential operators that satisfy commutator relationships, which we describe both in purely configurational and in full phase space setups. Standard operator calculus yields corresponding equilibrium hyperforce correlation sum rules for general observables and order parameters. Using Monte Carlos simulations we demonstrate explicitly the gauge invariance for finite shifting. We argue in favour of using the gauge invariance as a statistical mechanical construction principle for obtaining exact results and for formulating smart sampling algorithms.