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Limited regularity of a specific electronic reduced density matrix for molecules

Published 12 Sep 2023 in math-ph and math.MP | (2309.06318v3)

Abstract: We consider an electronic bound state of the usual, non-relativistic, molecular Hamiltonian with Coulomb interactions, fixed nuclei, and N electrons (N>1). Near appropriate electronic collisions, we prove that the (N-1)-particle electronic reduced density matrix is not smooth. To appear in Advances in Theoritical and Mathematical Physics.

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