Tuning the circularly polarized photoluminescence of chiral 2D perovskites by high pressure

Abstract: Chiral 2D perovskites are of great interest as circularly polarized photoluminescence materials, but these materials generally exhibit weak CPL under ambient conditions. Several studies have shown that the degree of CPL can be enhanced by using strong external magnetic fields or low temperature. Here we report a method to tune the circularly polarized photoluminescence of chiral 2D perovskites by utilizing extreme high pressure. The (S- and R-MBA)2PbI4 perovskites exhibited good optical tunability with pressure in term of PL wavelength, intensity and bandgap. Polarization-resolved photoluminescence measurements shown that the degree of CPL was increased from nearly zero at ambient pressure to as high as 10% at 8.5 GPa. ADXRD and Raman results indicated that the structural distortion and Increased interlayer coupling are responsible for the enhanced chirality when pressure is applied. Our findings provide a new approach to adjusting CPL materials and show potential applications in next generation of CPL devices.