Spin-splitting in electric-potential-difference antiferromagnetism (2307.05010v1)

Abstract: The antiferromagnetic (AFM) materials are robust to external magnetic perturbation due to missing any net magnetic moment. In general, the spin splitting in the band structures disappears in these antiferromagnets. However, the altermagnetism can achieve spin-split bands in collinear symmetry-compensated antiferromagnet with special magnetic space group. Here, we propose a new mechanism that can achieve spin splitting in two-dimensional (2D) Janus A-type AFM materials. Since the built-in electric field caused by Janus structure creates a layer-dependent electrostatic potential, the electronic bands in different layers will stagger, producing the spin splitting, which can be called electric-potential-difference antiferromagnetism (EPD-AFM). We demonstrate that Janus monolayer $\mathrm{Mn_2ClF}$ is a possible candidate to achieve the EPD-AFM by the first-principles calculations. It is proposed that the spin splitting can be tuned in EPD-AFM by piezoelectric effect. Our works provide a new design principle for generating spin polarization in 2D AFM materials.