Potential scatterings in $L^2$ space: (1) non-orthogonality of stationary states (2305.16939v4)

Abstract: Orthogonality of eigenstates of different energies and its implications in potential scattering are unlabeled. Scalar products of scattering states of different energies are found to have finite non-orthogonal terms in potentials of finite widths. Their superpositions have time-dependent norms, and are not suitable for isolate states. In these systems, a perturbative method and a variational method are viable methods for finding a rigorous transition probability that describes phenomena completely. In various exceptional potentials, an orthogonality is satisfied.