Humidity-induced glass transition of a polyelectrolyte brush creates switchable friction in air

Abstract: Polymer brushes have found extensive applications as responsive surfaces, particularly in achieving tunable friction in solvent environments. Despite recent interest in extending this technology to air environments, little is known about the impact of vapor absorption on friction. Considering polyelectrolyte brushes, we report findings that reveal, with increasing relative humidity, a trend of frictional shear forces decaying over two orders of magnitude only after achieving a critical humidity. However, water absorption, structure, and swelling of the brushes followed continuous trends with increasing humidity. In contrast, a humidity-induced glass transition occurred which caused a shift from dry to fluid-like sliding with the water-swollen brush acting as the lubricant. Below the glass transition, friction is large without regard to water concentration; thus, friction transitions sharply. This switching mechanism, shown to be a general property of the hygroscopic polymer, provides new opportunities for switchable friction or other surface actuation from vapor stimuli.