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Consistency of the structure of Legendre transform in thermodynamics with the Kolmogorov-Nagumo average (2206.04414v1)
Published 9 Jun 2022 in cond-mat.stat-mech, math-ph, and math.MP
Abstract: We show the robustness of the structure of Legendre transform in thermodynamics against the replacement of the standard linear average with the Kolmogorov-Nagumo nonlinear average to evaluate the expectation values of the macroscopic physical observables. The consequence of this statement is twofold: 1) the relationships between the expectation values and the corresponding Lagrange multipliers still hold in the present formalism; 2) the universality of the Gibbs equation as well as other thermodynamic relations are unaffected by the structure of the average used in the theory.
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