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Flexible confinement leads to multiple relaxation regimes in glassy colloidal liquids

Published 8 Nov 2020 in cond-mat.soft | (2011.04104v1)

Abstract: Understanding relaxation of supercooled fluids is a major challenge and confining such systems can lead to bewildering behaviour. Here we exploit an optically confined colloidal model system in which we use reduced pressure as a control parameter. The dynamics of the system are ``Arrhenius'' at low and moderate pressure, but at higher pressures relaxation is faster than expected. We associate this faster relaxation with a decrease in density adjacent to the confining boundary due to local ordering in the system enabled by the flexible wall.

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