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Richardson-Gaudin geminal wavefunctions in a Slater determinant basis

Published 17 Sep 2020 in physics.chem-ph | (2009.08349v1)

Abstract: Geminal wavefunctions have been employed to model strongly-correlated electrons. These wavefunctions represent products of weakly-correlated pairs of electrons and reasonable approximations are computable with polynomial cost. In particular, Richardson-Gaudin states have recently been employed as a variational ansatz. This contribution serves to explain the Richardson-Gaudin wavefunctions in the conventional language of quantum chemistry.

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