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On a dual representation of the Goldstone manifold

Published 10 Apr 2020 in physics.chem-ph and quant-ph | (2004.05047v1)

Abstract: An intrinsic wavefunction with a broken continuous symmetry can be rotated with no energy penalty leading to an infinite set of degenerate states known as a Goldstone manifold. In this work, we show that a dual representation of such manifold exists that is sampled by an infinite set of non-degenerate states. A proof that both representations are equivalent is provided. From the work of Peierls and Yoccoz (Proc. Phys. Soc. A {\bf 70}, 381 (1957)), it is known that collective states with good symmetries can be obtained from the Goldstone manifold using a generator coordinate trial wavefunction. We show that an analogous generator coordinate can be used in the dual representation; we provide numerical evidence using an intrinsic wavefunction with particle number symmetry-breaking for the electronic structure of the Be atom and one with $\hat{S}z$ symmetry-breaking for a H$_5$ ring. We discuss how the dual representation can be used to evaluate expectation values of symmetry-projected states when the norm $|\langle \Phi | \hat{P}q | \Phi \rangle|$ becomes very small.

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