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Fock-space relativistic coupled-cluster calculation of hyperfine induced $\bf {^1S_0 \rightarrow {^3P^o_0}}$ clock transition in Al$^+$

Published 25 Feb 2020 in physics.atom-ph | (2002.10705v3)

Abstract: We have developed an all-particle Fock-space relativistic coupled-cluster method to calculate the properties of two-valence atoms and ions. Using the method we compute the properties associated with hyperfine induced $1S_0 - 3Po_0$ clock transition in Al$+$. Our result of the $3Po_0$ metastable state life time, $20.20 \pm 0.91$ s, is in excellent agreement with the experimental value, $20.60 \pm 1.4$ s [Phys. Rev. Lett. {\bf 98}, 220801 (2007)]. Our studies show that the contributions from the triple excitations, and the corrections from the Breit interaction and QED effects are essential to obtain accurate clock properties in Al$+$.

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