Discovery Of Copper Catalyst For New Chemical Polishing Acid On Superconducting Niobium

Abstract: High field Q-slope (HFQS) seriously limits the high gradient performance of the buffered chemically polished (BCP) superconducting radio frequency (SRF) niobium cavities. The direct cause or mechanism is not yet fully understood. In our recent extensive data analysis, we concluded that the potential root cause could be nitrogen contamination on the surface. The nitric contamination could be created by nitric acid during BCP which uses the mixture of hydrofluoric acid, nitric acid, and phosphoric acid. Based on this thought, we started to develop a new chemical polishing acid that replaces the nitric acid by hydrogen peroxide. We have discovered that this new acid cannot provide smooth surface finishing, however adding copper catalyst allows this acid to provide a smooth surface similar to or even better than that from the conventional BCP. This paper first shows the significance of resolving HFQS, then summarizes our extensive data analysis results, and finally describes our discovery of the copper catalyst.