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Quantum Spin Liquid in a depleted triangular lattice Iridate Kx_xIry_yO2_2

Published 22 Aug 2019 in cond-mat.str-el and cond-mat.mtrl-sci | (1908.08475v1)

Abstract: We report discovery of a new iridate family K<em>x<em>xIry_yO2_2 with depleted triangular lattice planes made up of edge sharing IrO6_6 octahedra separated by K planes. Such a material interpolates between the triangular and honeycomb lattices and is a new playground for Kitaev physics. The materials are Mott insulators with y=1−x/4y = 1 - x/4. Physical property measurements for the x≈0.85x \approx 0.85 material are reported. Using magnetic susceptibility χ\chi versus temperature TT measurements we find S</em>eff=1/2S</em>{eff} = 1/2 moments interacting strongly with a Weiss temperature θ≈−180\theta \approx - 180~K and no magnetic order or spin freezing down to T=1.8T = 1.8~K\@. Heat capacity shows a broad maximum around $30$~K which is insensitive to magnetic fields and a TT-linear low temperature behaviour with γ∼10\gamma \sim 10~mJ/mol~K<sup>2<sup>2. These results are consistent with a gapless QSL state in K<em>0.85<em>{0.85}Ir</em>0.79</em>{0.79}O2_2.

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